| Oct 05, 2023 |
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(Nanowerk News) A research team under the direction of Prof. Dr Felix Deschler at Heidelberg University’s Institute for Physical Chemistry has developed a semiconductor that efficiently generates light and simultaneously gives that light a certain spin. According to the researchers, this chiral perovskite material has great technological potential that can be used for applications in optoelectronics, telecommunications, and information processing.
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The results were published in the journal Science Advances (“Bright Circularly-Polarized Photoluminescence in Chiral Layered Hybrid Lead-Halide Perovskites”).
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| Crystals of chiral hybrid perovskites. (Image: University of Heidelberg)
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Generating bright, circularly polarised light has long been a goal of materials science. It is considered exceedingly difficult to achieve a distinct chirality – which describes the rotation of light in a specific direction – as well as high photoluminescence quantum efficiency (PLQE). The PLQE value expresses the ability of a material to emit light. Inorganic semiconductors are able to emit high brightness but usually exhibit low light polarisation. In contrast, organic molecular semiconductors do have high polarisation, but their brightness is often limited by losses due to dark conditions.
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“Until now, a material that truly combines the high luminescence quantum efficiency of inorganic semiconductors and the strong chirality of organic molecular systems has been lacking,” reports Felix Deschler.
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To simultaneously obtain the desired brightness and high polarisation, the Heidelberg research group developed a hybrid metal-halide perovskite semiconductor with a layered structure. The scientists integrated a customised chiral organic molecule into the perovskite structure as a hybrid component. Using a small aromatic molecule with a precisely placed halogen atom in the aromatic ring gave rise to novel chiral perovskites with the structural designation R/S-3BrMBA2PbI4.
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“The ability to alter the structure so dramatically and yet still retain good material performance underscores the ability of perovskite materials to tolerate distortion in the crystal structure,” explains doctoral candidate Shangpu Liu.
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Owing to their greatly distorted crystal structures, chiral 3BrMBA2PbI4 perovskites exhibit a noticeably better degree of circularly polarised luminescence than other materials even at room temperature. Aided by sophisticated ultra-fast laser spectroscopy measurements, the researchers were able to unravel the processes behind the generation of this special light. The values found for polarisation and brightness exceed those known for previously used chiral semiconductors.
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The researchers were also able to show that the novel materials are extremely promising for applications that rely on circularly polarised light. They implemented the materials in light detectors that can record and differentiate the chirality of the incident light. Furthermore, the research team developed light-emitting diodes from which light can be generated from electricity.
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