| Apr 08, 2024 |
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(Nanowerk News) Transition metal telluride nanosheets have shown enormous promise for fundamental research and other applications across a range of different fields, but until now, mass fabrication has been impossible, leaving the material as something of a laboratory curiosity rather than an industrial reality. But a team of researchers has recently developed a novel exfoliation process – the use of chemical solutions to peel off thin layers from their parent compounds, creating atomically thin sheets – that looks set to finally deliver on the ultra-thin substance’s promise.
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The researchers describe their fabrication process in a study published in Nature (“Metal telluride nanosheets by scalable solid lithiation and exfoliation”).
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In the world of ultra-thin or two-dimensional materials, transition metal telluride (TMT) nanosheets have in recent years caused great excitement amongst chemists and materials scientists for their particularly unusual properties. These compounds, made of tellurium and any of the elements in the ‘middle’ of the periodic table (groups 3-12), enjoy a range of states from semi metallic to semiconducting, insulating and superconducting, and even more exotic states, as well as magnetic and unique catalytic activity.
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These properties offer a range of potential applications across electronics, energy storage, catalysis, and sensing. In particular, TMT nanosheets are being explored as novel electrode materials in batteries and supercapacitors due to their high conductivity and large surface area.
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TMT nanosheets can also be used as electrocatalysts for lithium-oxygen batteries, improving their efficiency and performance. Other potential applications in emerging technologies include photovoltaics and thermoelectrics, hydrogen production, and filtration and separation. They have even been found to display interesting quantum phenomena, such as quantum oscillations and giant magnetoresistance.
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“The list of industries that would enjoy significant efficiency improvements from the mass production of TMT nanosheets is extremely long,” said team leader WU Zhongshuai, a chemist with the Dalian Institute of Chemical Physics (DICP) of the Chinese Academy of Sciences. “This is why this 2D material is potentially so exciting.”
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Unfortunately, despite various attempts at exfoliation of high-quality TMT nanosheets, preserving high crystallinity while achieving large nanosheet size and ultrathin feature continues to be a significant challenge. The methods devised so far are not scalable due to long processing times. They also often require toxic chemicals. Thus, the properties of TMT nanosheets have remained an interesting laboratory phenomenon that cannot quite make the leap to mass production and industrial application.
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The team finally cracked this problem via a simplified process of lithiation, hydrolysis and finally the nanosheet exfoliation.
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First, a bulk quantity of metal telluride crystals was prepared using chemical vapor transport – a method commonly used in chemistry to transport solid compounds from one location to another using a carrier gas. When the reaction vessel is heated, the transporting agent vaporizes and carries the solid compound with it as a vapor. The vapor travels through the reaction vessel and may encounter a cooler surface, where the compound can deposit and form crystals. This allows for the controlled growth of crystals or very thin films of the desired compound. In this case, the prepared telluride crystals are then mixed with lithium borohydride.
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This process involves the placing of lithium ions in between the layers of the metal telluride crystals, leading to the formation of an intermediate, ‘lithiated’ compound. The lithiated intermediate compound is then rapidly drenched with water, which results in “exfoliation,” or stripping of the lithiated metal telluride crystals into nanosheets in seconds. Finally, the exfoliated metal telluride nanosheets are collected and characterized based on their shape and size, allowing them to be further processed into different forms such as films, inks and composites, depending on the desired application.
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The whole process takes just ten minutes for the lithiation and seconds for the hydrolysis. The method is capable of producing high-quality TMT nanosheets of varying desired thicknesses with very high yields.
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When testing the nanosheets, the researchers found that their charge storage, high-rate capacity, and stability made them promise for applications in lithium batteries and micro-supercapacitors. They believe that their method is essentially ready for commercialization.
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In future studies, the researchers want to characterize the properties and behavior of their nanosheets, as well as further refine and optimize the lithiation and exfoliation stages.
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